Electropolymerization and multifunctional properties of novel polypyrrole films embedded with Co nanoparticles

被引：13
|
作者：
Gao, Min [2 ]
Lu, Liying [1 ]
Xu, Xiaoguang [2 ]
Yao, Zhe [1 ]
Jiang, Yong [2 ]
机构：
[1] Univ Sci & Technol Beijing, Sch Chem & Biol Engn, Beijing 100083, Peoples R China
[2] Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
来源：
ELECTROCHIMICA ACTA | 2017年 / 228卷
基金：
美国国家科学基金会;
关键词：
polypyrrole films; electropolymerization; magnetic property; dielectricity; MAGNETIC-PROPERTIES; ELECTROMAGNETIC PROPERTIES; ELECTROCHEMICAL SYNTHESIS; NANOCOMPOSITES; METACOMPOSITES; MAGNETORESISTANCE; COMPOSITES; ELECTRODE;
D O I：
10.1016/j.electacta.2017.01.117
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
A novel electropolymerization process has been presented to prepare compact polypyrrole (PPy) polymer films embedded with different cobalt nanoparticle (Co NP) loadings by using cyclic voltammetry. An electropolymerization mechanism is suggested and further confirmed by Fourier transform infrared (FT-IR) spectroscopy and Raman spectroscopy of pure PPy and PPy polymer nanocomposites (PNCs). The PPy/Co PNCs exhibit unique multifunctional properties. Firstly, they are superparamagnets at room temperature, whose saturation magnetization can be controlled by modifying the concentration of Co NPs in the electrolyte solution. Secondly, they show not only semiconductor transportation behavior but also a negative rnagnetoresistance under external magnetic field. The permittivity of the PPy/Co PNCs switches from negative to positive with the increasing frequency. Both the outstanding magnetic and electrical properties make the PPy PNCs promising as one kind of microwave absorbing materials. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码：522 / 527
页数：6
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