New garnet compounds A 3 2+ B 2 2+ C4+V 2 5+ O12(A = Ca, Cd; B = Mg, Zn, Co, Ni, Cu, Mn, Cd; C = Ge, Si)

被引：11
|
作者：
Mill, B. V. [1 ]
Ronniger, G. [1 ]
Kabalov, Yu. K. [1 ]
机构：
[1] Moscow MV Lomonosov State Univ, Moscow 119992, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2014年 / 59卷 / 11期
关键词：
DES TERRES RARES; VANADATE GARNET; IONS;
D O I：
10.1134/S0036023614110151
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Garnet compounds A (3) (2+) B (2) (2+) C4+V (2) (5+) O-12 (A = Ca, Cd; B = Mg, Zn, Co, Ni, Cu, Mn, Cd; C = Ge, Si) (space group , Z = 8) have been prepared by solid-phase synthesis in air at 900-1250A degrees C. Most of these compounds melt incongruently or decompose in the solid phase. The isomorphic capacity of garnets and their homogeneity fields are discussed. The structures of Ca3Zn2GeV2O12 and Ca3Cu2GeV2O12 have been refined by the Rietveld method.
引用
收藏
页码：1208 / 1213
页数：6
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