Palladium-Catalyzed Carbonylative Transformation of C(sp3)-X Bonds

被引：156
|
作者：
Wu, Lipeng [1 ]
Fang, Xianjie [1 ]
Liu, Qiang [1 ]
Jackstell, Ralf [1 ]
Beller, Matthias [1 ]
Wu, Xiao-Feng [1 ]
机构：
[1] Univ Rostock, Leibniz Inst Katalyse, D-18059 Rostock, Germany
来源：
ACS CATALYSIS | 2014年 / 4卷 / 09期
关键词：
palladium catalyst; carbonylation; C(sp(3))-X bonds; cross-coupling; carbon monoxide; C-H BONDS; TRISULFONATED TRIPHENYLPHOSPHINE COMPLEXES; NOBLE METAL COMPOUNDS; ORGANIC ALLYL MOIETIES; BETA-KETO-ESTERS; CARBON-MONOXIDE; BETA; GAMMA-UNSATURATED ESTERS; ARYL HALIDES; OXIDATIVE CARBONYLATION; COUPLING REACTIONS;
D O I：
10.1021/cs500922x
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
During the last 50 years, the palladium-catalyzed carbonylation reactions underwent continuous development. Apart from carbonylation of aromatic (pseudo)-halide and alkene (C-sp(2)) compounds, the use of C(sp(3))-X compounds such as allyl compounds, benzyl compounds, and aliphatic alkanes have become the most useful tool for the synthesis of beta,gamma-unsaturated carbonyl compounds, aliphatic carboxylic acid, and their derivatives. The recently budding development in the area of palladium-catalyzed C(sp(3))-X (especially X = H) activation makes us feel it necessary to file a summary on the past, current contributions, and a prospective outlook on the palladium-catalyzed carbonylative transformation of C(sp(3)) X bonds, which is the focus of this review.
引用
收藏
页码：2977 / 2989
页数：13
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