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Synthesis and crystal structure of a new one-dimensional system with end-to-end single dicyanamide bridges between nickel(II) centres
被引:20
|作者:
Li, BL
[1
]
Ding, JG
Lang, JP
Xu, Z
Chen, JT
机构:
[1] Suzhou Univ, Dept Chem & Chem Engn, Suzhou 215006, Peoples R China
[2] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[3] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
关键词:
crystal structure;
dicyanamide;
hydrogen bonding;
nickel complex;
magnetic properties;
D O I:
10.1016/S0022-2860(02)00327-7
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
The complex [Ni(tn)(2)[N(CN)(2)}]ClO4 (m = trimethylenediamine) has been synthesized and the structure has been determined. The complex forms a one-dimensional chain structure via the bidentate bridging ligand dicyanamide. A two-dimensional networks is formed via interchain hydrogen bond interactions. (C) 2002 Elsevier Science B.V. All rights reserved.
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页码:175 / 179
页数:5
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