Synthesis and crystal structure of a new one-dimensional system with end-to-end single dicyanamide bridges between nickel(II) centres

被引:20
|
作者
Li, BL [1 ]
Ding, JG
Lang, JP
Xu, Z
Chen, JT
机构
[1] Suzhou Univ, Dept Chem & Chem Engn, Suzhou 215006, Peoples R China
[2] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[3] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
关键词
crystal structure; dicyanamide; hydrogen bonding; nickel complex; magnetic properties;
D O I
10.1016/S0022-2860(02)00327-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The complex [Ni(tn)(2)[N(CN)(2)}]ClO4 (m = trimethylenediamine) has been synthesized and the structure has been determined. The complex forms a one-dimensional chain structure via the bidentate bridging ligand dicyanamide. A two-dimensional networks is formed via interchain hydrogen bond interactions. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:175 / 179
页数:5
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