Synthesis and Crystal Structures of Two Zinc(II) Complexes with the Schiff Bases 2-[(3-Diethylaminopropylimino)methyl]phenol and 1-[(3-Diethylaminopropylimino)methyl]naphthalen-2-ol

被引：1

作者：

Lin, Hong-Wei ^{[1
]}

机构：

[1] Huaihua Univ, Dept Chem, Huaihua 418008, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2009年 / 39卷 / 02期

关键词：

synthesis; crystal structure; Schiff base; zinc(II) complex; NICKEL(II);

D O I：

10.1080/15533170902762595

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new structurally similar mononuclear Schiff base zinc(II) complexes, [ZnBr2L1] (1) and [ZnI2L2] (2) (L1 = 2-[(3-diethylaminopropylimino)methyl]phenol, L2 = 1-[(3-diethylaminopropylimino)methyl]naphthalen-2-ol), have been synthesized and characterized by elemental analysis, IR, and single crystal X-ray diffraction. The Zn atom in each of the complexes is four-coordinated by one phenolate oxygen atom and one imine nitrogen atom of a Schiff base ligand and by two halide ligands, forming a tetrahedral geometry. In the crystal structures of both complexes, molecules are linked through intermolecular hydrogen bonds of types N-H O, forming chains running along the b axis. The similar Schiff bases used in the preparation of the complexes with zinc(II) halides can result in the similar structures of the final products.

引用

页码：73 / 77

页数：5

共 50 条

[1] Synthesis, crystal structures, and biological activity of zinc(II) complexes derived from 4-bromo-2-[(3-diethylaminopropylimino)methyl]phenol
D. H. Shi
Z. L. Cao
W. W. Liu
R. B. Xu
L. L. Gao
Q. Zhang
Z. You
Russian Journal of Coordination Chemistry, 2013, 39 : 297 - 300
[2] Synthesis, crystal structures, and biological activity of zinc(II) complexes derived from 4-bromo-2-[(3-diethylaminopropylimino)methyl]phenol
Shi, D. H.
Cao, Z. L.
Liu, W. W.
Xu, R. B.
Gao, L. L.
Zhang, Q.
You, Z.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2013, 39 (03) : 297 - 300
[3] SYNTHESIS, CRYSTAL STRUCTURES AND UREASE INHIBITION OF ZINC(II) COMPLEXES DERIVED FROM 1-(((2-(PYRROLIDIN-1-YL)ETHYL)IMINO) METHYL)NAPHTHALEN-2-OL
Jiang, J.
Liang, P.
Deng, Y.
Zhao, H.
You, Z.
JOURNAL OF STRUCTURAL CHEMISTRY, 2023, 64 (11) : 2099 - 2110
[4] Synthesis, Crystal Structures and Urease Inhibition of Zinc(II) Complexes Derived from 1-(((2-(pyrrolidin-1-yl)ethyl)imino)methyl)Naphthalen-2-ol
J. Jiang
P. Liang
Y. Deng
H. Zhao
Z. You
Journal of Structural Chemistry, 2023, 64 : 2099 - 2110
[5] Transition Metal Complexes with the Schiff Base Ligand 1-{[2-(2-Hydroxyethylamino)ethylimino]methyl}naphthalen-2-ol
Niu, Mei-Ju
Li, Huan-Huan
Wang, Su-Na
Cao, Zhi-Qiang
Sun, Da-Wei
Dou, Jian-Min
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2013, 639 (02): : 414 - 423
[6] Crystal Structure of (E)-1-(((3-nitrophenyl)imino)methyl)naphthalen-2-ol
Kadafour, A. N. W.
Bala, M. D.
CRYSTALLOGRAPHY REPORTS, 2022, 67 (02) : 214 - 217
[7] Crystal Structure of (E)-1-(((3-nitrophenyl)imino)methyl)naphthalen-2-ol
A. N. W. Kadafour
M. D. Bala
Crystallography Reports, 2022, 67 : 214 - 217
[8] Synthesis, crystal structures, and antibacterial activities of two copper(II) complexes derived from 1-[(2-morpholin-4-ylethylimino)methyl]-naphthalen-2-ol
Sang, Ya-Li
Lin, Xue-Song
TRANSITION METAL CHEMISTRY, 2009, 34 (08) : 931 - 936
[9] Synthesis, crystal structures, and antibacterial activities of two copper(II) complexes derived from 1-[(2-morpholin-4-ylethylimino)methyl]-naphthalen-2-ol
Ya-Li Sang
Xue-Song Lin
Transition Metal Chemistry, 2009, 34 : 931 - 936
[10] Crystal structure of 4,4-bipyridine-containing complexes of copper(II) nitrate with 1-[(2-Hydroxyethylimino)methyl]naphthalen-2-ol and 2-[(2-hydroxyethylimino)methyl]phenol
Yu. M. Chumakov
V. L. Tsapkov
P. A. Petrenko
L. G. Popovski
Yu. A. Simonov
G. Bocelli
B. Ya. Antosyak
A. O. Paraschivescu
A. P. Gulea
Russian Journal of Coordination Chemistry, 2009, 35 : 504 - 511

← 1 2 3 4 5 →