Synthesis and characterization of a new metal-organic NLO material: Dibromo bis(triphenylphosphine oxide) mercury(II)

被引：8

作者：

Li, Li ^{[2
]}

Wang, Zhengping ^{[3
]}

Song, Xinyu ^{[1
]}

Sun, Sixiu ^{[1
]}

机构：

[1] Shandong Univ, Dept Chem, Jinan 250100, Shandong, Peoples R China

[2] Ningxia Univ, Coll Chem & Chem Engn, Ningxia 750021, Peoples R China

[3] Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2009年 / 72卷 / 04期

关键词：

NLO materials; Optical transmittance; SHG efficiency;

D O I：

10.1016/j.saa.2008.11.018

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

A new metal-organic nonlinear optical dibromo bis(triphenylphosphine oxide) mercury(II) (HgBr2(TPPO)(2), TPPO = triphenylphosphine oxide) crystal has been synthesized. Single-crystal X-ray diffraction reveals that HgBr2(TPPO)(2) crystallizes in the orthorhombic system, space group Pna2(1), a = 21.174 angstrom, b = 9.1979 angstrom, c = 17.468 angstrom, and Z = 4. The crystal was also characterized by FTIR spectroscopy, differential scanning calorimetry (DSC), thermal gravity analysis (TGA), and UV-vis-IR spectroscopy. Thermal analyses confirmed that the crystal is stable up to 151 degrees C. The transmission spectrum of the crystal shows that the lower cut off wavelength lies at 340 nm. The nonlinear optical (NLO) property of HgBr2(TPPO)(2) has been estimated by Kurtz-powder second harmonic generation (SHG) test. Crown Copyright (C) 2008 Published by Elsevier B.V. All rights reserved.

引用

页码：816 / 818

页数：3

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