Heteroligand copper(II) complexes with hydroxyethyleneiminodiacetic acid and bidentate nitrogen-containing ligands: Structures and properties

被引：1
|
作者：
Kutolei, D. A. [1 ,2 ]
Shtemenko, A. V. [1 ]
机构：
[1] Ukrainian State Univ Chem Technol, Dnepropetrovsk, Ukraine
[2] OOO NPTs REAKOM, Dnepropetrovsk, Ukraine
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2013年 / 39卷 / 12期
关键词：
CRYSTAL-STRUCTURE; COORDINATION;
D O I：
10.1134/S1070328413120026
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Procedures were proposed for the synthesis of the heteroligand copper(II) complexes with N-(2-hydroxyethyl)iminodiacetic acid (H(2)Heida) and 2-aminoethanol and ethylenediamine ligands. The optimal parameters of solutions for the isolation of ternary complexes were found. Heteroligand complexes Cu(Heida)En center dot 3H(2)O (I) and Cu(Heida)Mea (II) (En is ethylenediamine, and Mea is 2-aminoethanol) were examined by X-ray diffraction analysis. The thermal properties of complexes I and II and their thermodynamic stability in aqueous solutions were studied.
引用
收藏
页码：857 / 866
页数：10
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