Noncatalytic Polycondensation of L-Lactic Acid under Microwave Irradiation

被引：11

作者：

Hirao, Koichi ^{[1
]}

Masutani, Kazunari ^{[1
]}

Ohara, Hitomi ^{[1
]}

机构：

[1] Kyoto Inst Technol, R&D Ctr Biobased Mat, Sakyo Ku, Kyoto 6068585, Japan

来源：

JOURNAL OF CHEMICAL ENGINEERING OF JAPAN | 2009年 / 42卷 / 06期

关键词：

Microwave Irradiation; Noncatalysts; Polycondensation; Poly(Lactic Acid); POLY(L-LACTIC ACID); CATALYSTS;

D O I：

10.1252/jcej.09we040

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Noncatalytic polycondensation of L-lactic acid under microwave irradiation is compared with that under conventional heating. Under microwave irradiation, higher molecular weights of poly(L-lactic acid) can be obtained comparing with under conventional heating. Though the racemization of L-lactate was induced, it can be lowered at higher vacuum. As a result, higher molecular weight poly(L-lactic acid), comparing with conventional heating without increasing racemization, was synthesized with microwave irradiation.

引用

页码：417 / 419

页数：3

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