C60Cl6, C60Br8 and C60(NO2)6 as Selective Tools in Organic Synthesis

被引：13

作者：

Franco, Jimmy U. ^{[1
]}

Ell, John R. ^{[1
]}

Hilton, Amanda K. ^{[1
]}

Hammons, Justin C. ^{[1
]}

Olmstead, Marilyn M. ^{[1
]}

机构：

[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

来源：

FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES | 2009年 / 17卷 / 04期

关键词：

Halogenated fullerene; Selective synthesis; Chlorination; Bromination; Nitration; PORPHYRINS; C-60;

D O I：

10.1080/15363830903007960

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Reactions of C60Cl6, C60Br8 and C60(NO2)6 with arene substrates under mild conditions afford primarily monochlorinated, monobrominated or mononitrated organic products in high yield, often with greater selectivity and reactivity than with traditional halogenation or nitration methods. The reactions have the advantages of high stereoselectivity and facile removal and recovery of [60]fullerene. No metal catalysts, gases or harsh acids are required. These results demonstrate the versatility of the functionalized fullerenes as new synthetic tools for organic synthesis.

引用

页码：349 / 360

页数：12

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