Electrolytic partial fluorination of organic compounds 84 Anodic mono- and difluorination of benzylphosphonate derivatives

被引：8

作者：

Zagipa, Bakenova ^{[1
]}

Hidaka, Asami ^{[1
]}

Cao, Yi ^{[1
]}

Fuchigami, Toshio ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Elect Chem, Midori Ku, Yokohama, Kanagawa 2268502, Japan

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2006年 / 127卷 / 4-5期

关键词：

benzylphosphonate derivative; electrochemical fluorination; partial fluorination; fluorinated benzylphosphonate; PTP inhibitor;

D O I：

10.1016/j.jfluchem.2005.12.006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Anodic fluorination of benzylphosphonate derivatives was carried out under various electrolytic conditions to provide the corresponding alpha-mono- and/or alpha,alpha-difluoro-products in moderate to good yields. It was found that the selectivity of fluorinated products was depending on the molecular structures of the starting substrates and the electrolytic conditions. (C) 2006 Elsevier B.V. All rights reserved.

引用

页码：552 / 557

页数：6

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