Raman study on the structure of 3-mercaptopropionic acid monolayers on silver

被引：40
|
作者：
Kudelski, A [1 ]
机构：
[1] Univ Warsaw, Dept Chem, PL-02093 Warsaw, Poland
来源：
SURFACE SCIENCE | 2002年 / 502卷
关键词：
Raman scattering spectroscopy; self-assembly; silver; carboxylic acid;
D O I：
10.1016/S0039-6028(01)01947-1
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The influence of pH on the structure of 3-mercaptopropionic acid (MPA) monolayers on silver, and the changes in the structure of monolayers during adsorption and desorption of MPA molecules were investigated by surface-enhanced Raman scattering. The measurements were carried out in aqueous solutions. It was demonstrated that during the self-assembling of the monolayer there was a significant increase in the portion of a trans conformer of S-C-C chains of adsorbed MPA molecules, and a large portion of the COO- groups of the adsorbed MPA molecules was protonated. The strength of adsorbed acid clearly depends on its surface concentration. Desorption of MPA progressed at a slow rate and significant changes (reverse to the changes during adsorption) were observed after more than I h. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：219 / 223
页数：5
相关论文
共 50 条
  • [21] Potential Driven Deposition of Poly(diallyldimethylammonium chloride) onto the Surface of 3-Mercaptopropionic Acid Monolayers Assembled on Gold
    Sanders, Wesley
    Anderson, Mark R.
    LANGMUIR, 2008, 24 (22) : 12766 - 12770
  • [22] EFFECT OF PIRACETAM ON SEIZURES INDUCED BY 3-MERCAPTOPROPIONIC ACID IN RATS
    MARES, P
    ACTIVITAS NERVOSA SUPERIOR, 1981, 23 (03): : 219 - 221
  • [23] 3-Mercaptopropionic acid functionalization of titanium dioxide thin films
    Gomes, Orisson P.
    Azevedo Neto, Nilton F.
    Bronze-Uhle, Erika S.
    Trino, Luciana D.
    dos Santos, Cassio M.
    da Silva, Jose H. D.
    Lisboa-Filho, Paulo N.
    MATERIALS CHEMISTRY AND PHYSICS, 2019, 223 : 32 - 38
  • [24] 3-MERCAPTOPROPIONIC ACID, A POTENT INHIBITOR OF BETA-OXIDATION
    CUEBAS, D
    SABBAGH, E
    SCHULZ, H
    FEDERATION PROCEEDINGS, 1983, 42 (07) : 1855 - 1855
  • [25] ELECTROCORTICOGRAPHIC CHANGES INDUCED BY BICUCULLINE AND 3-MERCAPTOPROPIONIC ACID IN RATS
    ZOUHAR, A
    MARES, P
    KORYNTOVA, H
    PHYSIOLOGIA BOHEMOSLOVACA, 1984, 33 (06): : 576 - 576
  • [26] Characterization of 11-mercaptoundecanoic and 3-mercaptopropionic acids adsorbed on silver by surface-enhanced Raman scattering
    Marques, Flavia C.
    Oliveira, Gabriela P.
    Teixeira, Raissa A. R.
    Justo, Rodrigo M. S.
    Neves, Tatiana B. V.
    Andrade, Gustavo F. S.
    VIBRATIONAL SPECTROSCOPY, 2018, 98 : 139 - 144
  • [27] Control of Crystalline Forms and Morphologies for CaCO3 Crystals on 3-Mercaptopropionic Acid Self-assembled Monolayers
    Zhang Su
    Wang Hai-Shui
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2013, 29 (01) : 31 - 35
  • [28] POLAROGRAPHIC REDUCTION OF TIN(4) IN PRESENCE OF 3-MERCAPTOPROPIONIC ACID
    PHILLIPS, SL
    TOOMEY, RA
    ANALYTICAL CHEMISTRY, 1965, 37 (04) : 607 - &
  • [29] Distribution of the thiols glutathione and 3-mercaptopropionic acid in Connecticut lakes
    Hu, Haiying
    Mylon, Steven E.
    Benoit, Gaboury
    LIMNOLOGY AND OCEANOGRAPHY, 2006, 51 (06) : 2763 - 2774
  • [30] SEIZURES ELICITED BY 3-MERCAPTOPROPIONIC ACID IN RATS DURING ONTOGENESIS
    STURMOVA, H
    MARES, P
    PHYSIOLOGIA BOHEMOSLOVACA, 1981, 30 (05): : 462 - 462
12345