Bis(2,4,6-trimethylphenyl)zinc(II)

被引:4
|
作者
Krieck, Sven [1 ]
Goerls, Helmar [1 ]
Westerhausen, Matthias [1 ]
机构
[1] Univ Jena, Inst Inorgan & Analyt Chem, D-07743 Jena, Germany
关键词
DIARYLZINC; ZINC;
D O I
10.1107/S1600536809023186
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, [Zn(C9H11)(2)] or Mes(2)Zn (Mes = mesityl = 2,4,6-trimethylphenyl), crystallizes with a quarter of a molecule in the asymmetric unit. The Zn-II atom is in a strictly linear environment with a Zn-C bond length of 1.951 (5) angstrom. Due to the imposed 2/m symmetry, both aromatic rings are coplanar. One of the methyl groups is disordered over two equally occupied positions.
引用
收藏
页码:M809 / U1147
页数:7
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