Synthesis and Reactivity of Ruthenium Complexes Bearing Arsenic-Containing Arsenic-Nitrogen-Arsenic-Type Pincer Ligand

被引:26
|
作者
Tanabe, Yoshiaki [1 ]
Kuriyama, Shogo [1 ]
Arashiba, Kazuya [1 ]
Nakajima, Kazunari [1 ]
Nishibayashi, Yoshiaki [1 ]
机构
[1] Univ Tokyo, Inst Engn Innovat, Sch Engn, Bunkyo Ku, Tokyo 1138656, Japan
关键词
DINITROGEN COMPLEXES; AROMATIZATION-DEAROMATIZATION; MOLECULAR DINITROGEN; ELECTRONIC-STRUCTURE; CATALYTIC FORMATION; BOND ACTIVATION; MOLYBDENUM; ALCOHOLS; AMINES; AMMONIA;
D O I
10.1021/om5006116
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Dinuclear and mononuclear ruthenium complexes bearing an arsenic-containing arsenic-nitrogen-arsenic (ANA)-type pincer ligand are designed, prepared, and characterized by X-ray analyses. Both ruthenium complexes work as effective catalysts toward dehydrogenative transformations of alcohols.
引用
收藏
页码:5295 / 5300
页数:6
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