The second-harmonic generation in chalcogenide glass-ceramic doped with CdS nanocrystals

被引：3

作者：

Xue, Bai ^{[1
]}

Fan, Bo ^{[1
]}

Zhang, Xianghua ^{[1
]}

Quiquempois, Yves ^{[2
]}

Martinelli, Gilbert ^{[2
]}

Calvez, Laurent ^{[1
]}

机构：

[1] Univ Rennes 1, Equipe Verres & Ceram, Inst Sci Chim Rennes, F-35042 Rennes, France

[2] Univ Lille 1, Lab Phys Lasers Atomes & Mol, F-59655 Villeneuve Dascq, France

来源：

MATERIALS LETTERS | 2014年 / 132卷

关键词：

Optical materials and properties; Amorphous materials; Nanocrystalline materials; Sintering; CRYSTALLIZED GLASSES;

D O I：

10.1016/j.matlet.2014.05.200

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

An innovative way is proposed here to synthesize chalcogenide glass-ceramic by hot-pressing a combination of Ge20Sb12S68 glassy powder and non-linear CdS nano-particles. The cadmium sulfide nano-particles, which possess the second-harmonic generation property, were synthesized from basic cadmium solution strongly complexed by amine. The obtained glass-ceramics present homogeneous distribution of the crystals. The transmission reaches 30% at 5 mu m and up to 60% at 10.6 mu m. The second-harmonic generation at 0.9 mu m has been detected. This technique can overcome the uncontrollable hetero-crystallization which tends to occur in the glass-ceramics prepared by the conventional thermal treatment method. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：130 / 133

页数：4

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