The second-harmonic generation in chalcogenide glass-ceramic doped with CdS nanocrystals

被引：3
|
作者：
Xue, Bai [1 ]
Fan, Bo [1 ]
Zhang, Xianghua [1 ]
Quiquempois, Yves [2 ]
Martinelli, Gilbert [2 ]
Calvez, Laurent [1 ]
机构：
[1] Univ Rennes 1, Equipe Verres & Ceram, Inst Sci Chim Rennes, F-35042 Rennes, France
[2] Univ Lille 1, Lab Phys Lasers Atomes & Mol, F-59655 Villeneuve Dascq, France
来源：
MATERIALS LETTERS | 2014年 / 132卷
关键词：
Optical materials and properties; Amorphous materials; Nanocrystalline materials; Sintering; CRYSTALLIZED GLASSES;
D O I：
10.1016/j.matlet.2014.05.200
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
An innovative way is proposed here to synthesize chalcogenide glass-ceramic by hot-pressing a combination of Ge20Sb12S68 glassy powder and non-linear CdS nano-particles. The cadmium sulfide nano-particles, which possess the second-harmonic generation property, were synthesized from basic cadmium solution strongly complexed by amine. The obtained glass-ceramics present homogeneous distribution of the crystals. The transmission reaches 30% at 5 mu m and up to 60% at 10.6 mu m. The second-harmonic generation at 0.9 mu m has been detected. This technique can overcome the uncontrollable hetero-crystallization which tends to occur in the glass-ceramics prepared by the conventional thermal treatment method. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：130 / 133
页数：4
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