Thermodynamic length in a two-dimensional thermodynamic state space

被引:9
|
作者
Santoro, M [1 ]
机构
[1] Portland State Univ, Dept Math & Stat, Portland, OR 97207 USA
来源
JOURNAL OF CHEMICAL PHYSICS | 2004年 / 121卷 / 07期
关键词
D O I
10.1063/1.1774156
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The main goal of this paper is to reach an explicit formulation and possible interpretation of thermodynamic length in a thermodynamic state space with two degrees of freedom. Using the energy and entropy metric in a general form, we get explicit results about thermodynamic length along isotherms, its relation with work and with speed of sound. We also look at the relation between the determinants of the energy and entropy metrics and find that they differ by a factor of T-4. (C) 2004 American Institute of Physics.
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页码:2932 / 2936
页数:5
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