Trapping of the dichlorocarbene intermediate in the reaction of α-cyanobenzyl carbanion with carbon tetrachloride

被引：0
|
作者：
Cheng, JP [1 ]
Zheng, ZR [1 ]
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
来源：
CHINESE CHEMICAL LETTERS | 1998年 / 9卷 / 10期
关键词：
dichlorocarbene; S(N)2 vs. ET mechanism; CCl4;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
in Me2SO, an X-philic reaction took place between alpha-cyanobenzyl carbanion and CCl4. The intermediate dichlorocarbene was trapped by the primary product dicyanostilbene to give the alkene-carbene adduct, 1,1-dichloro-2,3-dicyano-2,3-diphenylcyclopropane.
引用
收藏
页码：895 / 896
页数：2
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