Access to Functionalized Luminescent Multi-2,2′:6′,2"-terpyridine Ligands

被引：5

作者：

Jacques, Alexandre ^{[1
]}

Cerfontaine, Simon ^{[1
]}

Elias, Benjamin ^{[1
]}

机构：

[1] Catholic Univ Louvain, IMCN, Mol Solides & React MOST, B-1348 Louvain La Neuve, Belgium

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 80卷 / 21期

关键词：

ORGANOMETALLIC SHEETS; TERPYRIDINE LIGAND; COPOLYMERS; ACID;

D O I：

10.1021/acs.joc.5b01897

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A one-pot synthesis of substituted multi-2,2':6',2 ''-terpyridines (multi-tpy) has been achieved using an acetylquaterpyridine precursor with various aryl aldehydes in basic media. This strategy enables ready access to functionalized terpyridines. Utilizing a Suzuki-type cross-coupling, larger structures such as tetra- or even hexa-tpy were obtained from our tri-tpy precursor. These macromolecular units are ideal building blocks for the construction of transition-metal-based supramolecular assemblies.

引用

页码：11143 / 11148

页数：6

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