Gold(I) phosphine-decorated 2,2′:6′,2"-terpyridine ligands

被引：8
|
作者：
Constable, Edwin C. [1 ]
Housecroft, Catherine E. [1 ]
Neuburger, Markus [1 ]
Schaffner, Silvia [1 ]
Shardlow, Ellen J. [1 ]
机构：
[1] Univ Basel, Dept Chem, CH-4056 Basel, Switzerland
来源：
POLYHEDRON | 2008年 / 27卷 / 01期
关键词：
gold(I); 2,2 ': 6 ',2 ''-terpyridine; phosphine; alkyne; ligand;
D O I：
10.1016/j.poly.2007.08.034
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis and characterization of the ligands R3PAu(1-H) (R =Bu-n, Ph) and (1-H)Au(mu-dppe)Au(1-H) (1 = HC CCH(2)Otpy, tpy = 2,2 ':6 ',2 ''-terpyridme) are reported. The single crystal structures of (Bu3PAu)-Bu-n(1-H) and (1-H)Au(mu-dppe)Au(1-H) have been determined, and weak hydrogen bonding rather than aurophilic interactions operate between the molecules in the solid state. (C) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码：65 / 70
页数：6
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