Catalytic enantioselective Michael addition of 1,3-dicarbonyl compounds to nitroalkenes catalyzed by well-defined chiral Ru amido complexes

被引：145
|
作者：
Watanabe, M [1 ]
Ikagawa, A [1 ]
Wang, H [1 ]
Murata, K [1 ]
Ikariya, T [1 ]
机构：
[1] Tokyo Inst Technol & Frontier Collaborat Res Ctr, Grad Sch Sci & Engn, Dept Appl Chem, Meguro Ku, Tokyo 1528552, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 36期
关键词：
D O I：
10.1021/ja046296g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Well-defined chiral Ru amido complexes promoted asymmetric Michael addition of 1,3-dicarbonyl compounds including malonates, β-keto esters, and 1,3-diketones to nitroalkenes to give the corresponding adducts with excellent ees and in excellent yields. Copyright © 2003 American Chemical Society.
引用
收藏
页码：11148 / 11149
页数：2
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