Catalytic enantioselective Michael addition of 1,3-dicarbonyl compounds to nitroalkenes catalyzed by well-defined chiral Ru amido complexes

被引：145

作者：

Watanabe, M ^{[1
]}

Ikagawa, A ^{[1
]}

Wang, H ^{[1
]}

Murata, K ^{[1
]}

Ikariya, T ^{[1
]}

机构：

[1] Tokyo Inst Technol & Frontier Collaborat Res Ctr, Grad Sch Sci & Engn, Dept Appl Chem, Meguro Ku, Tokyo 1528552, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 36期

关键词：

D O I：

10.1021/ja046296g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Well-defined chiral Ru amido complexes promoted asymmetric Michael addition of 1,3-dicarbonyl compounds including malonates, β-keto esters, and 1,3-diketones to nitroalkenes to give the corresponding adducts with excellent ees and in excellent yields. Copyright © 2003 American Chemical Society.

引用

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页码：11148 / 11149

页数：2

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