Synthesis of graphene/Ni-Al layered double hydroxide nanowires and their application as an electrode material for supercapacitors

被引:118
|
作者
Memon, Jamil [1 ,2 ]
Sun, Jinhua [1 ]
Meng, Dongli [1 ]
Ouyang, Wenzhu [1 ]
Memon, Mushtaque A. [1 ,2 ]
Huang, Yong [1 ]
Yan, Shouke [2 ]
Geng, Jianxin [1 ]
机构
[1] Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100190, Peoples R China
[2] Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China
基金
中国国家自然科学基金;
关键词
PERFORMANCE; OXIDE; ULTRACAPACITORS; NANOCOMPOSITE; CAPACITANCE; COMPOSITES; NANOSHEETS; GRAPHITE; GROWTH;
D O I
10.1039/c3ta14613h
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Graphene oxide (GO) as a template for the morphology controllable synthesis of inorganic particles has recently attracted enormous attention. In this study, we report the synthesis of graphene/Ni-Al layered double hydroxide (LDH) nanowires by using GO and adjusting the loading of urea in hydrothermal reactions. Transmission electron microscopy observation demonstrates that the graphene/Ni-Al LDH nanowires are composed of nano-sized Ni-Al LDH sheets. This finding demonstrates a new assembly form of LDH materials. Symmetric supercapacitors have been prepared by using the graphene/Ni-Al LDH nanowires as an electrode material. Compared to other Ni-Al LDH materials, the graphene/Ni-Al LDH nanowires exhibit much better performance as an electrode material for supercapacitors, due to the preferential conductive behaviour of the nanowire structures and the conductive networks formed by the nanowires in the corresponding electrodes.
引用
收藏
页码:5060 / 5067
页数:8
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