Variation of structural parameters in dimethylammonium manganese formate [(CH3)2NH2]Mn(HCOO)3 by substitution of transition metals (M = Zn, Co and Ni): by powder XRD method

被引：3
|
作者：
Sornadurai, D. [1 ]
Sarguna, R. M. [1 ]
Sridharan, V. [1 ,2 ]
机构：
[1] Indira Gandhi Ctr Atom Res, Condensed Matter Phys Div, Mat Sci Grp, Kalpakkam, Tamil Nadu, India
[2] HBNI, Kalpakkam, Tamil Nadu, India
来源：
POWDER DIFFRACTION | 2019年 / 34卷 / 02期
关键词：
Metal Organic Frameworks; Crystal Structure; Laue diffraction; Powder XRD method; Rietveld refinement; Shannon ionic radius;
D O I：
10.1017/S0885715619000307
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Variation of structural parameters of dimethylammonium manganese formate [(CH3)(2)NH2]Mn[(HCOO)(3)] upon substitution by the transition elements Zn, Co, and Ni is studied by powder X-ray diffraction (PXRD) technique. These metal-organic framework (MOF) crystals were grown by solvothermal method. The PXRD patterns of all MOFs exhibited rhombohedral structure. PXRD patterns of MOFs were analyzed using Rietveld refinement method. While the parent Mn-MOF and Mn0.9Zn0.1MOF are found to have similar structural parameters, Co and Ni substituted Mn-MOFs have smaller structural parameters than that of parent Mn-MOF. The reason for this variation in the lattice parameters is explained based on the Shannon ionic radii.
引用
收藏
页码：124 / 129
页数：6
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