Hydroformylation of olefins catalysed with bimetallic systems: HRh{P(OPh)(3)}(4)+cp(2)ZrH(CH(2)PPh(2)) and HRh(CO){P(OPh)(3)}(3)+cp(2)ZrH(CH(2)PPh(2))

被引：10

作者：

Trzeciak, AM

Ziotkowski, JJ

Choukroun, R

机构：

[1] UNIV WROCLAW,FAC CHEM,PL-50383 WROCLAW,POLAND

[2] CNRS,CHIM COORDINAT LAB,F-31077 TOULOUSE,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 525卷 / 1-2期

关键词：

hydroformylation; bimetallic system; rhodium; zirconium; olefins;

D O I：

10.1016/S0022-328X(96)06499-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The catalytic activity of bimetallic systems containing the rhodium complex HRh{P(OPh)(3)}(4) or HRh(CO){P(OPh)(3)}(3) and the Zr(IV) complex cp(2)ZrH(CH(2)PPh(2)) was tested in the hydroformylation reaction of 1-hexene and E-,Z-2-hexene. An increase in n/iso ratio (from 2.2 to 3.5 in the case of HRh{P(OPh)(3)}(4) and from 0.4 to 3.7 in the case of HRh(CO){P(OPh)(3)}(3)) was observed in 1-hexene hydroformylation in the presence of cp(2)ZrH(CH(2)PPh(2)).

引用

页码：145 / 149

页数：5

共 50 条

[1] INFLUENCE OF THE MODIFICATION OF THE LIGANDS ON HEX-1-ENE HYDROFORMYLATION CATALYZED BY [HRH(P(OPH)3)4] AND [HRH(CO)(P(OPH)3)3] - CATALYTIC ACTIVITY OF THE SYSTEM [HRH(P(OPH)3)4] + CP2ZR(CH2PPH2)2
TRZECIAK, AM
ZIOLKOWSKI, JJ
CHOUKROUN, R
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 420 (03) : 353 - 358
[2] REVERSIBLE ARM-OFF DISSOCIATION OF THE TRIPODAL MEC(CH2PPH2)3 IN HRH(CO)[MEC(CH2PPH2)3] UNDER HYDROFORMYLATION CONDITIONS
KISS, G
HORVATH, IT
[J]. ORGANOMETALLICS, 1991, 10 (11) : 3798 - 3799
[3] Preparation and characterisation of N(CH(2)PPh(2))(3), N(CH(2)PPh(2))(3)Mo(CO)(3) and [HN(CH(2)PPh(2))(3)Mo(CO)(3)]BF4
Walter, O
Huttner, G
Kern, R
[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1996, 51 (07): : 922 - 928
[4] 1,5-HEXADIENE SELECTIVE HYDROFORMYLATION REACTION CATALYZED WITH RH(ACAC)(P(OPH)(3))(2)/P(OPH)(3) AND RH(ACAC)(CO)(PPH(3))/PPH(3) COMPLEXES
TRZECIAK, AM
ZIOLKOWSKI, JJ
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 464 (01) : 107 - 111
[5] CONTRASTING THE CP(3)MCL/LI(CH2)(CH2)PPH(2) (M=U, TH) SYSTEMS - SYNTHESIS AND STRUCTURE OF CP(2)TH[(CH2)(CH2)PPH(2)](2)
CRAMER, RE
HITT, J
CHUNG, T
GILJE, JW
[J]. NEW JOURNAL OF CHEMISTRY, 1995, 19 (5-6) : 509 - 514
[6] CARBONYLVANADIUM COMPLEXES OF THE TRIPOD LIGANDS MEC(CH2PPH2)3 AND P(CH2CH2PPH2)3
REHDER, D
PUTTFARCKEN, U
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 184 (03) : 343 - 349
[7] HYDROGENATION AND ISOMERIZATION OF OLEFINS WITH DIPHENYLPHOSPHINOMETHYL HYDRIDE ZIRCONIUM, [CP2ZRH(CH2PPH2)]N, A SELECTIVE HOMOGENEOUS CATALYST
RAOULT, Y
CHOUKROUN, R
BASSOBERT, M
GERVAIS, D
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1992, 72 (01): : 47 - 58
[8] REACTIONS OF CPMO(CO)2[P(OPH)3]CH2OCH3 WITH ELECTROPHILES
GIBSON, DH
FRANCO, JO
RICHARDSON, JF
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1991, 201 : 117 - INOR
[9] SYNTHESIS OF CP(CO)COPT(PPH3)2(MU-CH2) AND CP2CO2PT(PPH3)2(MU-CO)2 FROM THE REACTION OF PT(PPH3)2(C2H4) WITH [CPCO(CO)]2(MU-CH2)
MACKLIN, PD
MIRKIN, CA
VISWANATHAN, N
WILLIAMS, GD
GEOFFROY, GL
RHEINGOLD, AL
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 334 (1-2) : 117 - 128
[10] Nitrosyl ruthenium complexes with general formula [RuCl3,(NO)(P-P)] (P-P={PPh(2)(CH2)(n)PPh(2)},n=1-3 and {PPh(2)-CH=CH-PPh(2)}). X-ray structure of [RuCl3(NO){PPh(2)(CH2)(3)PPh(2)}]
Batista, AA
Pereira, C
Queiroz, SL
deOliveira, LAA
Santos, RHD
Gambardella, MTD
[J]. POLYHEDRON, 1997, 16 (06) : 927 - 931

← 1 2 3 4 5 →