Hydrothermal synthesis of microporous materials with the direct incorporation of porphyrin molecules

被引：23
|
作者：
Khan, TA [1 ]
Hriljac, JA [1 ]
机构：
[1] Univ Birmingham, Sch Chem, Birmingham B15 2TT, W Midlands, England
来源：
INORGANICA CHIMICA ACTA | 1999年 / 294卷 / 02期
关键词：
molecular sieves; zeolites; aluminophosphates; porphyrins;
D O I：
10.1016/S0020-1693(99)00247-9
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The tetracationic water soluble compound 5,10,15,20-tetrakis(N-methyl-4-pyridyl)porphyrin, [H-2-TMPyP](4+), has been directly incorporated, during the hydrothermal synthesis, into the nanopores of two zeolites, namely X and Y, and the aluminophosphate VPI-5 framework. The resulting solids were characterised by a combination of X-ray powder diffraction, thermal gravimetric analysis and W-Vis spectroscopy. The implications for the use of these and related porphyrins as structure directing agents are discussed. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：179 / 182
页数：4
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