Fabrication of a Miniature Multi-Parameter Sensor Chip for Water Quality Assessment

被引:27
|
作者
Zhou, Bo [1 ,2 ]
Bian, Chao [1 ]
Tong, Jianhua [1 ]
Xia, Shanhong [1 ]
机构
[1] Chinese Acad Sci, Inst Elect, State Key Lab Transducer Technol, Beijing 100190, Peoples R China
[2] Univ Chinese Acad Sci, Sch Elect Elect & Commun Engn, Beijing 100080, Peoples R China
来源
SENSORS | 2017年 / 17卷 / 01期
关键词
water quality; MEMS; pH electrode; conductivity cell; iridium oxide; electrodeposition; AG/AGCL REFERENCE ELECTRODE; IRIDIUM OXIDE-FILMS; PH SENSORS; CONDUCTIVITY; STATE; TEMPERATURE; SYSTEM; SALINITY; PROBES; IRO2;
D O I
10.3390/s17010157
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Water contamination is a main inducement of human diseases. It is an important step to monitor the water quality in the water distribution system. Due to the features of large size, high cost, and complicated structure of traditional water determination sensors and devices, it is difficult to realize real-time water monitoring on a large scale. In this paper, we present a multi-parameter sensor chip, which is miniature, low-cost, and robust, to detect the pH, conductivity, and temperature of water simultaneously. The sensor chip was fabricated using micro-electro-mechanical system (MEMS) techniques. Iridium oxide film was electrodeposited as the pH-sensing material. The atomic ratio of Ir(III) to Ir(IV) is about 1.38 according to the X-ray photoelectron spectroscopy (XPS) analysis. The pH sensing electrode showed super-Nernstian response (67.60 mV/pH) and good linearity (R-2 = 0.9997), in the range of pH 2.22 to pH 11.81. KCl-agar and epoxy were used as the electrolyte layer and liquid junction for the solid-state reference electrode, respectively, and its potential stability in deionized water was 56 h. The conductivity cell exhibited a linear determination range from 21.43 mu S/cm to 1.99 mS/cm, and the electrode constant was 1.566 cm(-1). Sensitivity of the temperature sensor was 5.46 Omega/degrees C. The results indicate that the developed sensor chip has potential application in water quality measurements.
引用
收藏
页数:14
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