Densities and volumetric properties of the aqueous solutions of 2-amino-2-methyl-1-propanol, n-butyldiethanolamine and n-propylethanolamine at temperatures from 298.15 to 353.15 K

被引:56
|
作者
Chan, C
Maham, Y
Mather, AE [1 ]
Mathonat, C
机构
[1] Univ Alberta, Dept Chem & Mat Engn, Edmonton, AB T6G 2G6, Canada
[2] Setaram, F-60300 Caluire Et Cuire, France
基金
加拿大自然科学与工程研究理事会;
关键词
n-propylethanolamine; 2-amino-2-methyl-1-propanol; excess molar volumes; partial molar volumes; aqueous solutions;
D O I
10.1016/S0378-3812(01)00768-3
中图分类号
O414.1 [热力学];
学科分类号
摘要
Densities of the (water + 2-amino-2-methyl-1-propanol, AMP), (water + n-butyldiethanolamine, n-BDEA) and (water + n-propylethanolamine, n-PEA) mixtures have been measured over the full range of compositions at temperatures ranging from 298.15 to 353.15 K (except for pure AMP which is solid at 298.15 K). Results of these measurements have been used in calculating excess molar volumes of each system. The partial molar volumes and their derivatives with respect to temperature provide a basis for extending our understanding of molecular interactions in these (water + alkanolamine) systems. (C) 2002 Published by Elsevier Science B.V.
引用
收藏
页码:239 / 250
页数:12
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