A general method for synthesis of Se-trifluoromethyl esters through Iron-catalyzed trifluoromethylselenolation of acid chlorides

被引：22

作者：

Wang, Junwen ^{[1
]}

Zhang, Mengjia ^{[1
]}

Weng, Zhiqiang ^{[1
]}

机构：

[1] Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2017年 / 193卷

基金：

中国国家自然科学基金;

关键词：

Trifluoromethylselenolation; Acid chlorides; Se-trifluoromethyl esters; Copper; Iron; ARYL BORONIC ACIDS; ALKYL-HALIDES; COPPER; SELENOETHERS; REAGENTS; IODIDES; SULFUR; BONDS; MILD;

D O I：

10.1016/j.jfluchem.2016.11.006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A mild and efficient trifluoromethylselenolation of acid chlorides with [(bpy)Cu(SeCF3)](2) (1) in the presence of a catalytic amount of metallic iron powder is described. Easily available benzoyl chloride derivatives and alkyl acid chlorides are smoothly converted into the corresponding Se-trifluoromethyl esters in good to excellent yields. This simple transformation demonstrates a broad substrate scope with respect to acid chlorides, and is amenable to being carried out on gram scales. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：24 / 32

页数：9

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