Vapor-liquid critical properties of phenol and (C8 to C10) phenylalkanols

被引:8
|
作者
Nikitin, Eugene D.
Popov, Alexander P.
Yatluk, Yuri G.
机构
[1] Russian Acad Sci, Inst Thermal Phys, Ural Branch, Ekaterinburg 620016, Russia
[2] Russian Acad Sci, Inst Organ Synth, Ural Branch, Ekaterinburg 620219, Russia
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D O I
10.1021/je0604380
中图分类号
O414.1 [热力学];
学科分类号
摘要
The critical pressures and temperatures of phenol and three phenylalkanols C6H5(CH2)(n)OH with n = 2 to 4 have been measured. These substances are thermally unstable at their critical points. The pulse-heating method with ultralow residence times has been used. Residence times are from (0.03 to 1) ms. The experimental critical properties of phenol and phenylalkanols have been compared with the values calculated using the group-contribution methods by Constantinou and Gani and by Marrero and Gani.
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页码:315 / 317
页数:3
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