Molecular rheology of glassy polymers

被引:0
|
作者
Osaki, K [1 ]
Inoue, T [1 ]
机构
[1] Kyoto Univ, Inst Chem Res, Kyoto 6110011, Japan
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中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Simultaneous measurements of stress and birefringence in oscillatory deformation were revealed to provide information on the deformation of polymer chains and origin of stress in glassy state. The stress was composed of the glassy stress similar to that of ordinary glass-forming liquids and the rubbery stress due to the entropic force of chains. The relaxation behavior of these stress components were discussed in details.
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页码:67 / 70
页数:4
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