Growth, thermal and optical properties of a new nonlinear optical crystal: ZnBi2B2O7

被引：13

作者：

Li, Nan ^{[1
,2
]}

Fu, Peizhen ^{[1
]}

Wu, Yicheng ^{[1
]}

Zhang, Jianxiu ^{[1
]}

机构：

[1] Chinese Acad Sci, Tech Inst Phys & Chem, Beijing Ctr Crystal Res & Dev, Beijing 100190, Peoples R China

[2] Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China

来源：

JOURNAL OF CRYSTAL GROWTH | 2009年 / 311卷 / 13期

基金：

中国国家自然科学基金;

关键词：

X-ray diffraction; Growth from melt; Bismuth and zincum borate; Nonlinear optical materials;

D O I：

10.1016/j.jcrysgro.2009.04.016

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Single crystals of ZnBi2B2O7 (ZBBO) have been successfully grown by the top-seeded growth method from a high-temperature melt. The crystal was colorless and transparent with size of 15 x 10 x 5 mm(3). The orientation of ZBBO crystal has been discussed. The melting point, molar enthalpy of fusion, and molar entropy of fusion of the crystal were determined to be 964.02K, 110680.36 J mol(-1), and 113.92 J K-1 mol(-1), respectively. The transparency range of the crystal extends from 370 to 2100 nm. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：3476 / 3478

页数：3

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