trans-Diaquabis(6-methoxycarbonylpyridazine-3-carboxylato-κ2N,O)zinc(II) dihydrate

被引:1
|
作者
Starosta, Wojciech [1 ]
Leciejewicz, Janusz [1 ]
机构
[1] Inst Nucl Chem & Technol, PL-03195 Warsaw, Poland
关键词
PYRIDAZINE-3,6-DICARBOXYLIC ACID; CRYSTAL;
D O I
10.1107/S1600536809017115
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title centrosymmetric complex, [Zn(C7H5N2O4)(2)(H2O)(2)]center dot 2H(2)O, the Zn-II ion is coordinated in a trans mode by two symmetry-related bis-chelating 6-methoxycarbonyl-pyridazine-3-carboxylate ligands via N and O atoms, and by two aqua ligand O atoms in axial positions, in a slightly distorted octahedral environment. In the crystal structure, complex molecules are linked by intermolecular O-H center dot center dot center dot O hydrogen bonds between coordinated and solvent water molecules and carboxylate O atoms, forming molecular ribbons propagating along the a axis.
引用
收藏
页码:M640 / U416
页数:9
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