Lithium Plating on Graphite Negative Electrodes: Innovative Qualitative and Quantitative Investigation Methods

被引：90
|
作者：
Birkenmaier, Claudia [1 ,2 ]
Bitzer, Bernhard [3 ]
Harzheim, Matthias [4 ]
Hintennach, Andreas [1 ]
Schleid, Thomas [2 ]
机构：
[1] Daimler AG, D-71034 Boblingen, Germany
[2] Univ Stuttgart, Inst Inorgan Chem, D-70569 Stuttgart, Germany
[3] Daimler AG, D-89081 Ulm, Germany
[4] Daimler AG, D-70367 Stuttgart, Germany
来源：
JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2015年 / 162卷 / 14期
关键词：
IN-SITU MEASUREMENTS; LI-ION BATTERY; MECHANICAL-STRESS; CELLS; GENERATION; LITHIATION; INTERFACES; EVOLUTION; THICKNESS; SEM;
D O I：
10.1149/2.0451514jes
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
The effect of metallic lithium depositing on the negative electrode surface of a carbon-based lithium-ion battery instead of intercalating into the graphitic layers, namely lithium plating, can be assigned to charging at low temperatures and/or high currents. Cell parameters, such as performance and safety, are negatively influenced by this phenomenon. Elemental lithium deposited on the negative electrode requires more space than the intercalated compound and therefore increases the cell volume. Thus, the thickness changes during cycling can be used as a qualitative indicator for lithium plating. In this context, two different non-destructive experimental setups detecting the thickness profiles in situ are presented. Moreover, a quantitative titration technique to determine the exact amount cif lithium deposited is established. (C) 2015 The Electrochemical Society. All rights reserved.
引用
收藏
页码：A2646 / A2650
页数：5
相关论文
共 50 条
  • [31] Optical microscopic observation of graphite composite negative electrodes in all-solid-state lithium batteries
    Otoyama, Misae
    Sakuda, Atsushi
    Hayashi, Akitoshi
    Tatsumisago, Masahiro
    SOLID STATE IONICS, 2018, 323 : 123 - 129
  • [32] Mechanism of Surface Film Formation on Graphite Negative Electrodes and Its Correlation with Electrolyte in Lithium Secondary Batteries
    Jeong, Soon-Ki
    JOURNAL OF THE KOREAN ELECTROCHEMICAL SOCIETY, 2010, 13 (01): : 19 - 33
  • [33] Electrochemical characteristics of negative electrodes made of ozone-treated graphite for lithium-ion batteries
    Kulova, TL
    Kanevskii, LS
    Skundin, AM
    Sklovskii, DE
    Asryan, NA
    Bondarenko, GN
    RUSSIAN JOURNAL OF ELECTROCHEMISTRY, 2001, 37 (10) : 1017 - 1023
  • [34] Effect of carboxymethyl cellulose on aqueous processing of natural graphite negative electrodes and their electrochemical performance for lithium batteries
    Lee, JH
    Paik, U
    Hackley, VA
    Choi, YM
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (09) : A1763 - A1769
  • [35] Electrochemical characteristics of negative electrodes made of ozone-treated graphite for lithium-ion batteries
    Kulova, T.L.
    Kanevskij, L.S.
    Skundin, A.M.
    Sklovskij, D.E.
    Asryan, N.A.
    Bondarenko, G.N.
    Elektrokhimiya, 2001, 37 (10): : 1179 - 1187
  • [36] Performance tuning of lithium ion battery cells with area-oversized graphite based negative electrodes
    Dagger, Tim
    Kasnatscheew, Johannes
    Vortmann-Westhoven, Britta
    Schwieters, Timo
    Nowak, Sascha
    Winter, Martin
    Schappacher, Falko M.
    JOURNAL OF POWER SOURCES, 2018, 396 : 519 - 526
  • [37] Quantitative Phase Analysis and Structural Investigation of Graphite Anode for Lithium-Ion Batteries
    Farooq, Hammad
    Venvik, Hilde Johnsen
    Bandyopadhyay, Sulalit
    CHARACTERIZATION OF MINERALS, METALS, AND MATERIALS 2024, 2024, : 223 - 233
  • [38] An innovative phantom for quantitative and qualitative investigation of advanced x-ray imaging technologies
    Chiarot, CB
    Siewerdsen, JH
    Haycocks, T
    Moseley, DJ
    Jaffray, DA
    PHYSICS IN MEDICINE AND BIOLOGY, 2005, 50 (21): : N287 - N297
  • [39] Negative Electrodes in Rechargeable Lithium Ion Batteries - Influence of Graphite Surface Modification on the Formation of the Solid Electrolyte Interphase
    Buqa, H.
    Blyth, R. I. R.
    Golob, P.
    Evers, B.
    Schneider, I.
    Alvarez, M. V. Santis
    Hofer, F.
    Netzer, F. P.
    Ramsey, M. G.
    Winter, M.
    Besenhard, J. O.
    IONICS, 2000, 6 (3-4) : 172 - 179
  • [40] Negative electrodes in rechargeable lithium ion batteries — Influence of graphite surface modification on the formation of the solid electrolyte interphase
    H. Buqa
    R. I. R. Blyth
    P. Golob
    B. Evers
    I. Schneider
    M. V. Santis Alvarez
    F. Hofer
    F. P. Netzer
    M. G. Ramsey
    M. Winter
    J. O. Besenhard
    Ionics, 2000, 6 : 172 - 179
12345