Concise synthesis of a racemic and diastereomeric mixture of the sex pheromones of Matsucoccus pine scales

被引：165
|
作者：
Watanabe, H [1 ]
Watanabe, T [1 ]
Kitahara, T [1 ]
Mori, K [1 ]
机构：
[1] SCI UNIV TOKYO, DEPT CHEM, SHINJUKU KU, TOKYO 162, JAPAN
来源：
BIOSCIENCE BIOTECHNOLOGY AND BIOCHEMISTRY | 1997年 / 61卷 / 01期
关键词：
sex pheromone; pine scale; Matsucoccus; cyanation of allylic alcohol;
D O I：
10.1271/bbb.61.127
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
A short (3-5 steps) synthesis of a racemic and diastereomeric mixture of Matsucoccucs sex pheromones (1-3) is described. The key reaction is Lewis acid-mediated cyanation of symmetric tertiary alcohol 6 to afford common intermediate 7.
引用
收藏
页码：127 / 130
页数：4
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