A concise synthesis of the sex pheromones of Pine sawflies

被引：0
|
作者：
Wang, Zi-Kun [1 ]
Tian, Wei-Sheng
Pan, Xin-Fu
机构：
[1] Lanzhou Univ, Dept Chem, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2007年 / 27卷 / 07期
关键词：
sex pheromone of Pine sawfly; methyl (R)-5-bromo-4-methylpentanoate; coupling reaction;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Starting from methyl (R)-5-bromo-4-methylpentanoate (4) obtained from the waste in the degradation of steroid sapogenin, (2S,3S,7S)-3,7-dimethylpentadecan-2-yl acetate (2) and propionate (3) were synthesized via the coupling reaction of 4 with heptyl Grignard in 52% and 49% overall yields respectively.
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页码：866 / 869
页数：4
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