Green Synthesis of Aryl Thioethers through Cu-catalysed C-S Coupling of Thiols and Aryl Boronic Acids in Water

被引：3

作者：

Tu Peihua ^{[1
]}

Jiang Jun ^{[1
]}

Xiao Hongping ^{[1
]}

Li Xinhua ^{[1
]}

机构：

[1] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou 325035, Peoples R China

来源：

JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION | 2019年 / 34卷 / 04期

基金：

中国国家自然科学基金;

关键词：

green synthesis; Cu-catalysed C-S coupling; aryl boronic acids; water solvent; aryl thioether; BOND FORMATION; HYDROTHIOLATION; CHEMISTRY; ARYLATION; ALKYNES;

D O I：

10.1007/s11595-019-2148-1

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

An efficient, practical, highly selective and environmentally benign method is reported for the synthesis of aryl thioethers via the coupling of thiols with aryl boronic acids in the presence of NaOH and a catalytic amount of CuSO4 at 130 degrees C using water as a green solvent. The products were obtained in moderate to excellent yields; more importantly, the use of toxic ligands and solvents was avoided. A broad range of aryl boronic acids and scalable processes make this methodology valuable and versatile for the synthesis of a broad range of aryl sulfides.

引用

页码：987 / 993

页数：7

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