Sr0.5Ba0.5Nb2O6;
molten salt synthesis;
phase;
morphology;
D O I:
10.4028/www.scientific.net/KEM.317-318.69
中图分类号:
TQ174 [陶瓷工业];
TB3 [工程材料学];
学科分类号:
0805 ;
080502 ;
摘要:
In the present work, effects of different salts (NaCl, 0.5NaCl-0.5KCl and KCl) on molten-salt-synthesized Sr0.5Ba0.5Nb2O6 (SBN50) powder were explored. A variety of particle morphology, compositions and lattice parameters of SBN50 were investigated. The results showed that SBN50 particles synthesized in NaCl salt have the finest diameter (0.1-0.2 mu m) and the highest aspect ratio (around 10), while the particles from 0.5NaCl-0.5KCl salt show the coarsest diameter (0.2-0.3 mu m) and the lowest aspect ratio (around 5). If only using KCl salt, trace Sr2Nb2O7 normally co-exists with SBN50 phase. In addition, Na+ and K+ cations from salts are easily incorporated with SBN structure and reach a very high content.
机构:
Russian Acad Sci, Fed Res Ctr, Southern Sci Ctr, Rostov Na Donu 344006, Russia
Southern Fed Univ, Res Inst Phys, Rostov Na Donu 344090, RussiaRussian Acad Sci, Fed Res Ctr, Southern Sci Ctr, Rostov Na Donu 344006, Russia
Pavlenko, A. V.
Zakharchenko, I. N.
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Southern Fed Univ, Res Inst Phys, Rostov Na Donu 344090, RussiaRussian Acad Sci, Fed Res Ctr, Southern Sci Ctr, Rostov Na Donu 344006, Russia
Zakharchenko, I. N.
Kudryavtsev, Yu. A.
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IPN, CINVESTAV, Solid State Elect Sect, Av Inst Politecn Nacl 2508, Mexico City, DF, MexicoRussian Acad Sci, Fed Res Ctr, Southern Sci Ctr, Rostov Na Donu 344006, Russia
Kudryavtsev, Yu. A.
Kiseleva, L. I.
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Russian Acad Sci, Fed Res Ctr, Southern Sci Ctr, Rostov Na Donu 344006, RussiaRussian Acad Sci, Fed Res Ctr, Southern Sci Ctr, Rostov Na Donu 344006, Russia
Kiseleva, L. I.
Alikhadzhiev, S. Kh.
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机构:
Chechnya State Univ, Grozny 364024, Chechnya, RussiaRussian Acad Sci, Fed Res Ctr, Southern Sci Ctr, Rostov Na Donu 344006, Russia
机构:
Russian Acad Sci, Fed Res Ctr, Southern Sci Ctr, Rostov Na Donu, RussiaRussian Acad Sci, Fed Res Ctr, Southern Sci Ctr, Rostov Na Donu, Russia
Stryukov, D., V
Pavlenko, A., V
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机构:
Russian Acad Sci, Fed Res Ctr, Southern Sci Ctr, Rostov Na Donu, Russia
Southern Fed Univ, Inst Phys, Rostov Na Donu, RussiaRussian Acad Sci, Fed Res Ctr, Southern Sci Ctr, Rostov Na Donu, Russia
Pavlenko, A., V
Matyash, Ya Yu
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Russian Acad Sci, Fed Res Ctr, Southern Sci Ctr, Rostov Na Donu, RussiaRussian Acad Sci, Fed Res Ctr, Southern Sci Ctr, Rostov Na Donu, Russia
Matyash, Ya Yu
Kiseleva, L., I
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Russian Acad Sci, Fed Res Ctr, Southern Sci Ctr, Rostov Na Donu, RussiaRussian Acad Sci, Fed Res Ctr, Southern Sci Ctr, Rostov Na Donu, Russia