Deintercalation of Zero-Valent Metals from Two-Dimensional Layered Chalcogenides

被引：26
|
作者：
Wang, Mengjing [1 ]
Al-Dhahir, Isabel [1 ]
Appiah, Jude [1 ]
Koski, Kristie J. [2 ]
机构：
[1] Brown Univ, Dept Chem, 324 Brook St Box H, Providence, RI 02912 USA
[2] Univ Calif Davis, Dept Chem, 1 Shields Ave, Davis, CA 95616 USA
来源：
CHEMISTRY OF MATERIALS | 2017年 / 29卷 / 04期
关键词：
CHEMICAL INTERCALATION; TIN(II); COPPER;
D O I：
10.1021/acs.chemmater.6b04918
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A general solution-based approach to deintercalate zero-valent tin and copper from two-dimensional layered chalcogenides is presented using a one-step comproportionation reduction oxidation reaction. The reaction is performed between the intercalated zero-valent metal and high oxidation state metal cations (Sn4+ and Cu2+) dissolved in acetone. This chemistry is shown to work for a variety of layered chalcogenides with differing morphologies and crystallinity. Copper and tin are deintercalated from powders of MoS2, MoSe2, NbSe2, and WS2 and crystalline nanoribbons of Bi2Se3, In2Se3, and GeS. This chemistry achieves a general route to remove zero-valent tin and copper from 2D layered chalcogenides.
引用
收藏
页码：1650 / 1655
页数：6
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