Preparation of chiral polydiacetylene film from achiral monomers using circularly polarized light

被引：41
|
作者：
Manaka, Takaaki [1 ]
Kon, Hideki [1 ]
Ohshima, Yuki [1 ]
Zou, Gang [1 ]
Iwamoto, Mitsumasa [1 ]
机构：
[1] Tokyo Inst Technol, Dept Phys Elect, Meguro Ku, Tokyo 1528552, Japan
来源：
CHEMISTRY LETTERS | 2006年 / 35卷 / 09期
关键词：
D O I：
10.1246/cl.2006.1028
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Formation of chiral polydiacetylene (PDA) film using circularly polarized light (CPL) was demonstrated for the first time. Commercially available achiral derivative of diacetylene was used to prepare the vacuum evaporated monomer film and it was polymerized using ultra-violet CPL. Chiral source was only CPL, and the irradiation of left- and right-CPL definitely yielded opposite chiral polymer.
引用
收藏
页码：1028 / 1029
页数：2
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