Metal-Free Oxidative Double C(sp3)-C(sp3) Coupling of 1,3-Dicarbonyl Compounds and N,N-Dimethylanilines

被引：4
|
作者：
Huang, Ling [1 ]
Cao, Dongdong [1 ]
Pan, Jie [1 ]
Fang, Lingjia [1 ]
Wang, Qianqian [1 ]
Chen, Dingben [1 ,2 ]
Yang, Jianguo [1 ]
机构：
[1] Taizhou Univ, Sch Pharmaceut & Mat Engn, 1139 Shifu Rd, Taizhou 318000, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2020年 / 362卷 / 24期
关键词：
cross-dehydrogenative coupling; double C(sp(3))-C(sp(3)) coupling; 1,3-dicarbonyl compounds; metal-free; tandem reaction; C-C-BOND; TERTIARY-AMINES; H ACTIVATION; FUNCTIONALIZATION; METHYLENATION; COBALT; SCOPE;
D O I：
10.1002/adsc.202000974
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Herein, metal-free oxidative tandem cross-dehydrogenative coupling of 1,3-dicarbonyl compounds with N,N-dimethylanilines is developed. The reaction affords two new C(sp(3))-C(sp(3)) bonds in one pot. A broad range of ss-dicarbonyl compounds and N,N-dimethylanilines were compatible, and the desired products were synthesized in moderate-to-good yields.
引用
收藏
页码：5653 / 5657
页数：5
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