Synthesis of stereochemically defined (E)-cinnamyl alcohol derivatives from the Baylis-Hillman adducts

被引：0
|
作者：
Kim, HS [1 ]
Kim, TY [1 ]
Lee, KY [1 ]
Chung, YM [1 ]
Lee, HJ [1 ]
Kim, JN [1 ]
机构：
[1] Chonnam Natl Univ, Dept Chem, Kwangju 500757, South Korea
来源：
TETRAHEDRON LETTERS | 2000年 / 41卷 / 15期
关键词：
allylic alcohols; Baylis-Hillman adducts; trifluoroacetic acid;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The reaction of the Baylis-Hillman adducts 1a-g and trifluoroacetic acid at 30-70 degrees C gave the rearranged cinnamyl alcohols 2a-g stereoselectively in moderate yields. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：2613 / 2616
页数：4
相关论文
共 50 条
  • [21] Single-step stereoselective synthesis of (E)- and (Z)-allylamines from acetyl derivatives of Baylis-Hillman adducts
    Das, B
    Mahender, G
    Chowdhury, N
    Banerjee, J
    SYNLETT, 2005, (06) : 1000 - 1002
  • [22] An expedient synthesis of β-phenyl substituted Baylis-Hillman and Aza-Baylis-Hillman adducts
    Kim, Seong Jin
    Lee, Hyun Seung
    Kim, Jeong Mi
    Kim, Jae Nyoung
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2008, 29 (01): : 265 - 268
  • [23] Synthesis of cyclopropane derivatives starting from the Baylis-Hillman adducts using sulfur ylide chemistry
    Lee, KY
    Kim, SC
    Kim, JN
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2006, 27 (02): : 319 - 321
  • [24] SYNTHESIS OF FUSED PYRIMIDONE DERIVATIVES OF 4-PYRONES FROM THE ACETATES OF BAYLIS-HILLMAN ADDUCTS
    Shahrisa, A.
    Ghasemi, Z.
    CHEMISTRY OF HETEROCYCLIC COMPOUNDS, 2010, 46 (01) : 30 - 36
  • [25] Heck Arylations of Baylis-Hillman Adducts
    Le Bras, Jean
    Muzart, Jacques
    SYNTHESIS-STUTTGART, 2011, (22): : 3581 - 3591
  • [26] An Expedient Synthesis of Cinnamyl Fluorides from Morita-Baylis-Hillman Adducts
    Lim, Cheol Hee
    Kim, Se Hee
    Lee, Hyun Ju
    Kim, Hyung Jin
    Kim, Jae Nyoung
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2013, 34 (03): : 993 - 996
  • [27] Application of TMSOTf in the Baylis-Hillman adducts
    Ravichandran, S
    SYNTHETIC COMMUNICATIONS, 2001, 31 (15) : 2345 - 2350
  • [28] A highly efficient stereoselective synthesis of (Z)- and (E)-allyl iodides from Baylis-Hillman adducts
    Das, B
    Majhi, A
    Banerjee, J
    Chowdhury, N
    Venkateswarlu, K
    TETRAHEDRON LETTERS, 2005, 46 (46) : 7913 - 7915
  • [29] Biocatalytic Reductions of Baylis-Hillman Adducts
    Walton, Adam Z.
    Conerly, W. Colin
    Pompeu, Yuri
    Sullivan, Bradford
    Stewart, Jon D.
    ACS CATALYSIS, 2011, 1 (09): : 989 - 993
  • [30] Novel synthesis of indolylquinoline derivatives via the C-alkylation of Baylis-Hillman adducts
    Ramesh, Chintakunta
    Kavala, Veerababurao
    Raju, B. Rama
    Kuo, Chun-Wei
    Yao, Ching-Fa
    TETRAHEDRON LETTERS, 2009, 50 (28) : 4037 - 4041
12345