Activation of σ(C-H) bonds in C6H5CH=NCH2CH2SEt induced by platinum(II).: X-ray crystal structure of [Pt{C6H4CH=NCH2CH2SEt}Cl]

被引:38
|
作者
Riera, X
Caubet, A
López, C
Moreno, V
Solans, X
Font-Bardía, M
机构
[1] Univ Barcelona, Fac Quim, Dept Quim Inorgan, E-08028 Barcelona, Spain
[2] Univ Barcelona, Fac Geol, Dept Cristallog Mineral & Diposits Minerals, E-08028 Barcelona, Spain
关键词
D O I
10.1021/om990602v
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The study of the reactivity of C6H5CH=NCH2CH2SEt with platinum(II) salts is reported. These studies have established the relative importance of the factors governing the formation of [Pt{C6H4CH=NCH2CH2SEt}Cl], in which the ligand acts as a [C,N,S](-) terdentate group.
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页码:1384 / 1390
页数:7
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