CYCLOMETALATED PLATINUM(II) AND PLATINUM(IV) COMPOUNDS OF N-BENZYLIDENE-2-CHLOROBENZYLAMINE - CRYSTAL-STRUCTURE OF [PTME(PPH3)(C6H4CH=NCH2C6H4CL-2)]

被引：16

作者：

CRESPO, M ^{[1
]}

SOLANS, X ^{[1
]}

FONTBARDIA, M ^{[1
]}

机构：

[1] UNIV BARCELONA,DEPT CRISTALLOG MINERAL & DIPOSITS MINERALS,E-08028 BARCELONA,SPAIN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 483卷 / 1-2期

关键词：

PLATINUM; X-RAY STRUCTURE; CYCLOMETALATED PLATINUM(II); (IV); IMINE; OXIDATIVE ADDITION;

D O I：

10.1016/0022-328X(94)87163-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The cyclometallated compound [PtMe(SMe2)(C6H4CH=NCH2C6H4Cl-2)] (1) undergoes a displacement reaction with PPh3 to yield a cyclometallated platinum(II) compound [PtMe(PPh3)(C6H4CH=NCH2C6H4Cl-2)] (2), which has been characterized crystallographically. Complex 2 crystallizes in the monoclinic space group C2/c, with a = 38.402(4) angstrom, b = 7.993(3) angstrom, c = 18.563(3) angstrom, beta = 101.34(3)-degrees and Z = 8. The reaction of 1 with 1,2-bis(diphenylphosphino)ethane (dppe) yields [PtMe(dppe)-(C6H4CH=NCH2C6H4Cl-2)] (3) containing an unidentate C donor imine ligand and a chelating diphosphine. Oxidative addition of methyl iodide to 1 yields a cyclometallated platinum(IV) compound [PtMe2I(SMe2)(C6H4CH=NCH2C6H4Cl-2)] (4), which undergoes a displacement reaction of SMe2 by PPh3 to yield [PtMe2I(PPh3)(C6H4CH=NCH2C6H4Cl-2)] (5). Compound 5 can also be obtained by oxidative addition of methyl iodide to 2. The stereochemistry of compounds 4 and 5 is discussed.

引用

页码：187 / 192

页数：6

共 50 条

[1] Regioselective activation of C-H bonds of naphthyl imines at platinum(II).: Crystal structures of [PtMe{1-(2′-ClC6H4CH2NCH)C10H6}PPh3] and [PtMe{2-(2′-ClC6H4CH2NCH)C10H6}PPh3]
Crespo, M
Font-Bardía, M
Pérez, S
Solans, X
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 642 (1-2) : 171 - 178
[2] Activation of σ(C-H) bonds in C6H5CH=NCH2CH2SEt induced by platinum(II).: X-ray crystal structure of [Pt{C6H4CH=NCH2CH2SEt}Cl]
Riera, X
Caubet, A
López, C
Moreno, V
Solans, X
Font-Bardía, M
[J]. ORGANOMETALLICS, 2000, 19 (07) : 1384 - 1390
[3] Steric and electronic effects on the regioselective formation of platinum(II) metallacycles: crystal structure of [PtMe(3-MeC6H3CH=NCH2C6H5)(PPh3$ /)]
[J]. J Organomet Chem, 1 (29):
[4] Cyclometalated platinum(II) compounds with fluorinated iminic ligands. Synthesis and reactivity tuning. Crystal structures of the compounds [PtMe(RCH=NCH2C6H6)(PPh3)] (R = 2,3,4-C6HF3 and 2,3-C6H2F2)
Crespo, M.
Solans, X.
Font-Bardia, M.
[J]. Organometallics, 1995, 14 (01):
[5] CYCLOMETALATED PLATINUM(II) COMPOUNDS WITH FLUORINATED IMINIC LIGANDS - SYNTHESIS AND REACTIVITY TUNING - CRYSTAL-STRUCTURES OF THE COMPOUNDS [PTME(RCH=NCH2C6H5)(PPH3)] (R=2,3,4-C6HF3 AND 2,3-C6H2F2)
CRESPO, M
SOLANS, X
FONTBARDIA, M
[J]. ORGANOMETALLICS, 1995, 14 (01) : 355 - 364
[6] Steric and electronic effects on the regioselective formation of platinum(II) metallacycles: Crystal structure of [PtMe(3-MeC(6)H(3)CH=NCH2C6H5)(PPh(3))]
Crespo, M
Solans, X
FontBardia, M
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 509 (01) : 29 - 36
[7] Cyclometallated platinum compounds with N-benzylidenebenzylamines bearing trifluoromethyl groups.: Crystal structure of [PtMe{3-(CF3) C6H3CH=NCH2Ph}(PPh3)]
Crespo, M
Solans, X
Font-Bardia, M
[J]. POLYHEDRON, 1998, 17 (10) : 1651 - 1657
[8] Cyclometallated platinum compounds with chiral imines.: Crystal structure of [PtMe(2-FC6H3CH=N-(S)-CHMePh)(PPh3)]
Crespo, M
Solans, X
Font-Bardía, M
[J]. POLYHEDRON, 1998, 17 (22) : 3927 - 3934
[9] LIGAND-EXCHANGE REACTIONS IN CYCLOPALLADATED COMPLEXES OF BENZYLIDENEANILINES, CRYSTAL-STRUCTURE OF [PD(C6H4CH=NC6H5)BR(PPH3)2]
GRANELL, J
SAINZ, D
SALES, J
SOLANS, X
FONTALTABA, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (09): : 1785 - 1790
[10] Solution decomposition of platinum(II) fluoride cations;: single-crystal structure of [Pt(PPh3)2(C6H4PPh2)][SbF6]•CD2Cl2
Clark, HCS
Fawcett, J
Holloway, JH
Hope, EG
Peck, LA
Russell, DR
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (07): : 1249 - 1252

← 1 2 3 4 5 →