Three-Component Spiro Heterocyclization of Pyrrolediones with Malononitrile and Cyclic Enols

被引:3
|
作者
Sal'nikova, T. V. [1 ]
Dmitriev, M. V. [1 ]
Bushmeleva, E. V. [1 ]
Silaichev, P. S. [1 ]
Maslivets, A. N. [1 ]
机构
[1] Perm State Univ, Ul Bukireva 15, Perm 614990, Russia
基金
俄罗斯基础研究基金会;
关键词
MOLECULAR-STRUCTURE; CRYSTAL; 1H-PYRROLE-2,3-DIONES; ACETONITRILES; CONDENSATION; IRIDOIDS; ETHYL;
D O I
10.1134/S1070428018040073
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Ethyl 4,5-dioxo-2-phenyl-4,5-dihydro-1H-pyrrole-3-carboxylates reacted with malononitrile and five-membered cyclic enols, indan-1,3-dione and cyclopentane-1,3-dione to give 1-substituted ethyl 2-amino-3- cyano-2',5-dioxo-5'-phenyl-1',2'-dihydro-5H-spiro[indeno[1,2-b]pyran-4,3'-pyrrole]-4'-carboxylates and ethyl 2-amino-3-cyano-2',5-dioxo-5'-phenyl-1',2',6,7-tetrahydro-5H-spiro[cyclopenta[b]pyran-4,3'-pyrrole]-4'-carboxylates, respectively.
引用
收藏
页码:564 / 567
页数:4
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