In situ evolved gas analysis assisted thermogravimetric (TG-FTIR and TG/DTA-MS) studies on non-activated copper benzene-1,3,5-tricarboxylate

被引：26

作者：

Doman, Andrea ^{[1
]}

Madarasz, Janos ^{[2
]}

Laszlo, Krisztina ^{[1
]}

机构：

[1] Budapest Univ Technol & Econ, Dept Phys Chem & Mat Sci, H-1521 Budapest, Hungary

[2] Budapest Univ Technol & Econ, Dept Inorgan & Analyt Chem, H-1521 Budapest, Hungary

来源：

THERMOCHIMICA ACTA | 2017年 / 647卷

关键词：

HKUST-1; Metal organic framework; MOF; Simultaneous TG/DTA-MS; TG-FTIR; XRD; METAL-ORGANIC FRAMEWORK; CU-BTC; ADSORPTION; HKUST-1; CU-3(BTC)(2); PERFORMANCE; ACTIVATION; CU(II); VISUALIZATION; TEMPERATURE;

D O I：

10.1016/j.tca.2016.11.013

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The results of a complete thermogravimetric study of copper benzene-1,3,5-tricarboxylate (Cu-BTC or HKUST-1) are reported here together with mass spectrometry (MS) and Fourier transform infrared spectroscopy (FTIR) analyses of the evolved gases up to 800 degrees C. Oxidative and inert conditions were applied to reveal the stoichiometry of the as-received synthesis product. In spite of using a water-ethanol mixture during the synthesis and the filtration, only water is retained in the pores. It is proposed that the thermolytic release of ethanol in the temperature range 150-250 degrees C originates from ethanol-benzene-1,3,5-tricarboxylate (BTC) esters situated on the surface of the HKUST-1 crystal, and which limit the size of the developing crystals during the synthesis. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：62 / 69

页数：8