Iridium complexes with aliphatic, non-innocent pincer ligands

被引：24

作者：

Polukeev, Alexey V. ^{[1
]}

Wendt, Ola F. ^{[1
]}

机构：

[1] Lund Univ, Dept Chem, Ctr Anal & Synth, POB 124, S-22100 Lund, Sweden

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2018年 / 867卷

基金：

瑞典研究理事会;

关键词：

Pincer complexes; Iridium; Non-innocent ligands; Metal-ligand cooperation; Catalysis; C-H ACTIVATION; CATALYTIC-ACTIVITY; HYDRIDE COMPLEXES; METAL COOPERATION; BOND ACTIVATION; CARBENE COMPLEX; HYDROGEN-BONDS; CARBON BONDS; REACTIVITY; DEHYDROGENATION;

D O I：

10.1016/j.jorganchem.2017.12.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Pincer complexes attract considerable attention both as interesting objects for fundamental studies and efficient catalysts. This review describes a relatively new offshoot of the field - namely, the chemistry of iridium complexes with aliphatic PCsp3P non-innocent pincer ligands. High flexibility, often combined with possibility to activate internal CeH bonds, offers several new patterns of metal-ligand cooperation; some of them were successfully used in catalysis of acceptorless alcohol dehydrogenation, olefin hydroformylation and deuterium exchange, others opened up for remarkable stoichiometric reactions. (c) 2017 Elsevier B.V. All rights reserved.

引用

页码：33 / 50

页数：18

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