Peracetylated sugar derivatives show high solubility in liquid and supercritical carbon dioxide

被引：78
|
作者：
Potluri, VK
Xu, JH
Enick, R
Beckman, E
Hamilton, AD
机构：
[1] Yale Univ, Dept Chem, New Haven, CT 06520 USA
[2] Univ Pittsburgh, Dept Chem & Petr Engn, Pittsburgh, PA 15261 USA
来源：
ORGANIC LETTERS | 2002年 / 4卷 / 14期
关键词：
D O I：
10.1021/ol026007y
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
[GRAPHICS] Acetylated sugars derivatives exhibit high solubility in liquid and supercritical carbon dioxide (scCO(2)). Peracetylated sorbitol and beta-D-galactose are soluble under mild conditions in scCO(2), high pressures are required to dissolve peracetylated beta-cyclodextrin, and peracetoxyalkyl chains impart CO2-solubility to amides.
引用
收藏
页码：2333 / 2335
页数：3
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