Bis(2,2′-bipyridine N,N′-dioxide)bis(tricyanomethanido)manganese(II)

被引：3
|
作者：
Luo, Jun [1 ]
Yang, Feng [1 ]
Qiu, Li-Juan [1 ]
Wang, Xin-Xia [2 ]
Liu, Bao-Shu [1 ]
机构：
[1] Second Mil Med Univ, Sch Pharm, Shanghai 200433, Peoples R China
[2] Second Mil Med Univ, Eastern Hepatobiliary Surg Hosp, Dept Pharm, Shanghai 200438, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
基金：
中国国家自然科学基金;
关键词：
MAGNETIC-PROPERTIES; TRICYANOMETHANIDE; C(CN)(3)(-); TCM(-);
D O I：
10.1107/S1600536809013828
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title complex, [Mn(C4N3)(2)(C10H8N2O2)(2)], the Mn-II atom lies on an inversion center and is coordinated by two 2,2'-bipyridine N,N'-dioxide (dpdo) molecules and two tricyanomethanide (tcm) ligands to form a distorted octahedral geometry. Weak intermolecular C-H center dot center dot center dot O or C-H center dot center dot center dot N hydrogen bonds, involving either the O atom of the dpdo molecule and the pyridyl H atom, or the N atom of the tcm anion and the pyridyl H atom, result in the formation of a three-dimensional network structure.
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页码：M547 / U761
页数：11
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