Selective Propene Oligomerization with Nickel(II)-Based Metal-Organic Frameworks

被引：86
|
作者：
Mlinar, Anton N. [1 ]
Keitz, Benjamin K. [2 ]
Gygi, David [2 ]
Bloch, Eric D. [2 ]
Long, Jeffrey R. [2 ]
Bell, Alexis T. [1 ]
机构：
[1] Univ Calif Berkeley, Dept Chem & Biomol Engn, Berkeley, CA 94720 USA
[2] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
来源：
ACS CATALYSIS | 2014年 / 4卷 / 03期
关键词：
metal-organic frameworks; catalysis; oligomerization; propene; nickel; HYDROGEN STORAGE; H-2; ADSORPTION; CARBON-DIOXIDE; ETHYLENE; DIMERIZATION; CATALYSTS; NI; POLYMER; COMPLEX; ETHENE;
D O I：
10.1021/cs401189a
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Two Ni2+-containing metal-organic frameworks, Ni-2(dobdc) and Ni-2(dobpdc), are shown to be active for the oligomerization of propene in the gas phase. The metal-organic frameworks exhibit activity comparable to Ni2+-exchanged aluminosilicates but maintain high selectivity for linear oligomers. Thus, these frameworks should enable the high yielding synthesis of linear propene oligomers for use in detergent and diesel fuel applications.
引用
收藏
页码：717 / 721
页数：5
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